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Room temperature CO2 reduction to solid carbon species on liquid metals featuring atomically thin ceria interfaces

Room temperature CO2 reduction to solid carbon species on liquid metals featuring atomically thin ceria interfaces
Nature Communicationsvolume 10, Article number: 865 (2019) | Download Citation
Negative carbon emission technologies are critical for ensuring a future stable climate. However, the gaseous state of CO2 does render the indefinite storage of this greenhouse gas challenging. Herein, we created a liquid metal electrocatalyst that contains metallic elemental cerium nanoparticles, which facilitates the electrochemical reduction of CO2 to layered solid carbonaceous species, at a low onset potential of −310 mV vs CO2/C. We exploited the formation of a cerium oxide catalyst at the liquid metal/electrolyte interface, which together with cerium nanoparticles, promoted the room temperature reduction of CO2. Due to the inhibition of van der Waals adhesion at the liquid interface, the electrode was remarkably resistant to deactivation via coking caused by solid carbonaceous species. The as-produced solid carbonaceous materials could be utilised for the fabrication of high-performance capacitor electrodes. Overall, this liquid metal enabled electrocatalytic process at room temperature may result in a viable negative emission technology.

Room temperature CO<sub>2</sub> reduction to solid carbon species on liquid metals featuring atomically thin ceria interfaces

What is Cerium?

Cerium chemical element, atomic number 58, Periodic table - chart of all chemical elements

Cerium is a malleable, soft, ductile, iron-grey metal, slightly harder than lead. It is very reactive: it tarnishes readily in the air, it oxidizes slowly in cold water and rapidly in hot water. It dissolves in acids. It can burn when heated or scratched with a knife.


The metal is used as a core for the carbon electrodes of arc lamps, for incandescent mantles for gas lighting. Cerium is used in aluminium and iron alloys, in stainless steel as a precipitation hardening agent, to make permanent magnets. Cerium oxide is part of the catalyst of catalytic converters used to clean up exhaust vehicles, it also catalyzes the reduction of nitrogen oxides (NOx) to nitrogen gas. All new cars are now equipped with catalytic conveter which consist in a ceramic or metal substrate, a coating of aluminium and cerium oxides and a layer of finely dispersed metal such as platinum or rhodium, which is the active surface.
Cerium sulphide (Ce2S3) is likely to replace cadmium in red pigments for containers, toys, household wares and crates, since cadmium is now considered environmentally undesiderable.
Other uses of cerium are in flat-screen televisions, low-energy light bulbs and magnetic-optic compact discs, in chromium plating. The use of cerium is still growing, due to the fact that it is suited to produce catalysers and to polish glass.

Cerium in the environment

Cerium is the most abundant of the rare earth elements. It makes up about 0.0046 % of the Earth's crust by weight. Cerium comes mainly from the major lanthanide ores but some is obtained from perovskite, a titanium mineral and allanite, both of which can have enough cerium to make them viable sources. Production amounts to 23.000 tonnes a year, but this amount is likely to increase since more and more cerium is used nowadays.

Health effects of cerium
Cerium is one of the rare chemicals, that can be found in houses in equipment such as colour televisions, fluorescent lamps, energy-saving lamps and glasses. All rare chemicals have comparable properties.
Cerium is mostly dangerous in the working environment, due to the fact that damps and gasses can be inhaled with air. This can cause lung embolisms, especially during long-term exposure. Cerium can be a threat to the liver when it accumulates in the human body.
Cerium has no know biological role, but it has been noted that cerium salts stimulate metabolism.
Environmental effects of cerium
Cerium is dumped in the environment in many different places, mainly by petrol-producing industries. It can also enter the environment when household equipment is thrown away. Cerium will gradually accumulate in soils and water soils and this will eventually lead to increasing concentrations in humans, animals and soil particles.

With water animals cerium causes damage to cell membranes, which has several negative influences on reproduction and on the functions of the nervous system.
Thanks to its use in catalytic converters cerium is slowly improving the atmosphere of cities, or wherever diesel engines operates. Diesel engines emits particulates, carbon particles only a few micrometers in diameter. One way to reduce particulates emissions is trap them in a ceramic filter and then burn them off. If a little cerium oxide is added to the fuel itself, it will catalyse the burning of the particulates and eliminate them.

Read more: Cerium (Ce) - Chemical properties, Health and Environmental effects